{"id":189,"date":"2024-10-31T15:28:34","date_gmt":"2024-10-31T14:28:34","guid":{"rendered":"http:\/\/wwww.icp.universite-paris-saclay.fr\/capri\/?page_id=189"},"modified":"2025-10-29T17:33:13","modified_gmt":"2025-10-29T16:33:13","slug":"measurement-of-reaction-cross-sections","status":"publish","type":"page","link":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/en\/reactivity-of-ions\/measurement-of-reaction-cross-sections\/","title":{"rendered":"Measurement of Reaction Cross Sections of Ion-Molecule Reactions, Effects of Internal and Collision Energy for Astrochemistry and Industrial Plasma Chemistry"},"content":{"rendered":"<div id=\"pl-189\"  class=\"panel-layout\" ><div id=\"pg-189-0\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-189-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-189-0-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Measurement of Reaction Cross Sections of Ion-Molecule Reactions, Effects of Internal and Collision Energy for Astrochemistry and Industrial Plasma Chemistry<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<\/div>\n<\/div><\/div><div id=\"panel-189-0-0-1\" class=\"so-panel widget widget_sow-editor\" data-index=\"1\" ><div class=\"panel-widget-style panel-widget-style-for-189-0-0-1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Roland Thissen (Senior Researcher), Claire Romanzin (Associate Prof), Christian Alcaraz (Benevolent Researcher)<\/p>\n<\/div>\n<\/div><\/div><\/div><div id=\"panel-189-0-0-2\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p><a href=\"https:\/\/www.icp.universite-paris-saclay.fr\/en\/cerises-2\/\" target=\"_blank\" rel=\"noopener\">The CERISES platform<\/a>, associated with \u00a0<a href=\"https:\/\/www.synchrotron-soleil.fr\/en\/beamlines\/desirs\" target=\"_blank\" rel=\"noopener\">the DESIRS beamline<\/a> of <a href=\"https:\/\/www.synchrotron-soleil.fr\/en\" target=\"_blank\" rel=\"noopener\">the SOLEIL synchrotron<\/a> provides a unique approach for the detailed description of the reactive dynamics of small molecular systems. This enables the simulation of elementary acts as they may occur in planetary atmospheres or the interstellar medium, while also providing absolute reaction cross sections.<\/p>\n<p>By utilizing a radical source, the team has successfully reacted CH3+ in an adjustable internal energy state with small oxygenated molecules. They have also investigated the effects of selected states on the reactivity of O2+ with small hydrocarbons and volatile organic compounds, and explored the effect of isomerism by comparing the reactivity of HCO+ and COH+.<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-189-1\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-189-1-0\"  class=\"panel-grid-cell\" ><div id=\"panel-189-1-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"3\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Notable results from these studies include<\/p>\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Measurement of the Absolute Cross Section for the Formation of SH+: After the collision between S+ and H2, which holds significant astrophysical interest.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-189-1-1\"  class=\"panel-grid-cell\" ><div id=\"panel-189-1-1-0\" class=\"so-panel widget widget_sow-image panel-first-child\" data-index=\"4\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-189\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-1.png\" width=\"368\" height=\"254\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-1.png 368w, https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-1-300x207.png 300w\" sizes=\"(max-width: 368px) 100vw, 368px\" title=\"C 2-1-1\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><div id=\"panel-189-1-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"5\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: center;\"><em>Integral cross section for the reaction S+ + H2 \u2192 HS+. The red line corresponds to experimental data, and the black lines represent the theoretical cross sections for the formation of SH+.. [<a href=\"https:\/\/universite-paris-saclay.hal.science\/ICPO\/hal-04658975v1\" target=\"_blank\" rel=\"noopener\">Zanchet2024<\/a>]<\/em><\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-189-2\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-189-2-0\"  class=\"panel-grid-cell\" ><div id=\"panel-189-2-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"6\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Innovative Method for Highlighting Collision-Induced Isomerization of an Ion.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-189-2-1\"  class=\"panel-grid-cell\" ><div id=\"panel-189-2-1-0\" class=\"so-panel widget widget_sow-image panel-first-child\" data-index=\"7\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-189\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-2.png\" width=\"364\" height=\"274\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-2.png 364w, https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-2-300x226.png 300w\" sizes=\"(max-width: 364px) 100vw, 364px\" title=\"C 2-1-2\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><div id=\"panel-189-2-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"8\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: center;\"><em>Differences in time-of-flight spectra recorded in the CERISES instrument for the reaction between the ion HOC+ and four neutral targets, allowing for the highlighting and quantification of a collision-induced isomerization process. [<a href=\"https:\/\/universite-paris-saclay.hal.science\/ICPO\/hal-04603550v1\" target=\"_blank\" rel=\"noopener\">Solem2024<\/a>]<\/em><\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-189-3\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-189-3-0\"  class=\"panel-grid-cell\" ><div id=\"panel-189-3-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"9\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Structure of C8H6+ Isomers as a Function of Ion Internal Energy: Revisited by studying their reactivity with two neutral targets, propyne and allene.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-189-3-1\"  class=\"panel-grid-cell\" ><div id=\"panel-189-3-1-0\" class=\"so-panel widget widget_sow-image panel-first-child\" data-index=\"10\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-189\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-3.png\" width=\"626\" height=\"258\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-3.png 626w, https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-3-300x124.png 300w\" sizes=\"(max-width: 626px) 100vw, 626px\" title=\"C 2-1-3\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><div id=\"panel-189-3-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"11\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: center;\"><em>Absolute reaction cross sections for the formation of a mass 115 ion by reacting C8H6+ with allene. The three colors correspond to the precursor of C8H6+, which can be either phenylacetylene (red), naphthalene (yellow), or azulene (green). [<a href=\"https:\/\/universite-paris-saclay.hal.science\/ICPO\/hal-04420281v1\">Rossi2024<\/a>]<\/em><\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-189-4\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-189-4-0\"  class=\"panel-grid-cell\" ><div id=\"panel-189-4-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"12\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Combined Theoretical and Experimental Study of the Differentiated Reactivity of Two Isomers H2CNH+ and HCNH2+ with Propene.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-189-4-1\"  class=\"panel-grid-cell\" ><div id=\"panel-189-4-1-0\" class=\"so-panel widget widget_sow-image panel-first-child\" data-index=\"13\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-189\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-4.png\" width=\"936\" height=\"346\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-4.png 936w, https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-4-300x111.png 300w, https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-content\/uploads\/sites\/2\/2024\/10\/C-2-1-4-768x284.png 768w\" sizes=\"(max-width: 936px) 100vw, 936px\" title=\"C 2-1-4\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><div id=\"panel-189-4-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"14\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: center;\"><em>Absolute reaction cross sections for the two ionic isomers HCNH2+ and H2CNH+ with propene as a function of collision energy. The colors correspond to the different observed products. [<a href=\"https:\/\/universite-paris-saclay.hal.science\/ICPO\/hal-04691938v1\">Richardson2024<\/a>]<\/em><\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-189-5\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-189-5-0\"  class=\"panel-grid-cell\" ><div id=\"panel-189-5-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"15\" ><div class=\"panel-widget-style panel-widget-style-for-189-5-0-0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Collaborations<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Daniela Ascenzi (University of Trento, Italy), Miroslav Polasek and Jan Zabka (Heyrovsky Institute of Physical Chemistry, Prague, Czech Republic), Wolf Geppert (Stockholm University, Sweden), Emilie Zins (MONARIS, Sorbonne University, Paris), Ugo Jacovella (ISMO, U P Saclay), St\u00e9phane Pasquiers (LPGP, U P Saclay), Alexandre Zanchet (Complutense University of Madrid, Spain), Karoly Vekey (Budapest University, Hungary), James Lyons (Arizona State University, USA).<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>","protected":false},"excerpt":{"rendered":"<p>Roland Thissen (Senior Researcher), Claire Romanzin (Associate Prof), Christian Alcaraz (Benevolent Researcher) The CERISES platform, associated with \u00a0the DESIRS beamline of the SOLEIL synchrotron provides a unique approach for the detailed description of the reactive dynamics of small molecular systems. This enables the simulation of elementary acts as they may occur in planetary atmospheres or&hellip;&nbsp;<a href=\"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/en\/reactivity-of-ions\/measurement-of-reaction-cross-sections\/\" rel=\"bookmark\">Lire la suite &raquo;<span class=\"screen-reader-text\">Measurement of Reaction Cross Sections of Ion-Molecule Reactions, Effects of Internal and Collision Energy for Astrochemistry and Industrial Plasma Chemistry<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":170,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"off","neve_meta_content_width":100,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","footnotes":""},"class_list":["post-189","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/pages\/189","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/comments?post=189"}],"version-history":[{"count":7,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/pages\/189\/revisions"}],"predecessor-version":[{"id":493,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/pages\/189\/revisions\/493"}],"up":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/pages\/170"}],"wp:attachment":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/capri\/wp-json\/wp\/v2\/media?parent=189"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}