{"id":123,"date":"2024-11-12T18:10:09","date_gmt":"2024-11-12T17:10:09","guid":{"rendered":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/?page_id=123"},"modified":"2024-11-12T18:10:09","modified_gmt":"2024-11-12T17:10:09","slug":"ft-icr-mass-spectrometer-at-very-high-resolution","status":"publish","type":"page","link":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/en\/ft-icr-mass-spectrometer-at-very-high-resolution\/","title":{"rendered":"FT-ICR Mass Spectrometer at Very High Resolution"},"content":{"rendered":"<div id=\"pl-123\"  class=\"panel-layout\" ><div id=\"pg-123-0\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-123-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-123-0-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"0\" ><div class=\"panel-widget-style panel-widget-style-for-123-0-0-0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">FT-ICR Mass Spectrometer at Very High Resolution  --  [E10]<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Infrared Spectroscopy of Ions Integrated with Mass Spectrometry \/ 7T FT-ICR<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><div id=\"pg-123-1\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-123-1-0\"  class=\"panel-grid-cell\" ><div id=\"panel-123-1-0-0\" class=\"so-panel widget widget_sow-image panel-first-child panel-last-child\" data-index=\"1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-123\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E10.jpg\" width=\"776\" height=\"440\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E10.jpg 776w, https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E10-300x170.jpg 300w, https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E10-768x435.jpg 768w\" sizes=\"(max-width: 776px) 100vw, 776px\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><\/div><div id=\"pgc-123-1-1\"  class=\"panel-grid-cell\" ><div id=\"panel-123-1-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>The room is equipped with a hybrid FT-ICR mass spectrometer featuring a 7T magnet (Bruker Apex Qe), coupled with the Free Electron Laser, an OPO\/OPA tabletop laser (2.5 -5 \u00b5m), and a CO2 laser (10.6 \u00b5m). This setup allows for deriving IR spectra of ions within the mass spectrometer. Ions are vaporized using an ESI or nanoESI source. The Ar introduction line used for CID (Collision-Induced Dissociation) fragmentation has been modified to introduce neutral molecules directly into the collision cell, enabling ion-molecule reactions. <strong>This device is part of the national INFRANALYTICS network and PEPR LUMA.<\/strong><\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-123-2\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-123-2-0\"  class=\"panel-grid-cell\" ><div id=\"panel-123-2-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child\" data-index=\"3\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Disciplines<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Molecular Physicochemistry<\/li>\n<li>Analytical Chemistry<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><div id=\"panel-123-2-0-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"4\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Complementary Techniques<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>High-resolution mass spectrometry (100,000)<\/li>\n<li>Tandem mass spectrometry (MS2) and MSn<\/li>\n<li>ECD<\/li>\n<li>Nanospray<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-123-2-1\"  class=\"panel-grid-cell\" ><div id=\"panel-123-2-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"5\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Applications<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Two-color IR Spectroscopy<\/li>\n<li>Characterization of ions produced by ECD (Electron Capture Dissociation)<\/li>\n<li>Study of reaction mechanisms via spectroscopic intermediates<\/li>\n<li>Characterization of products in complex mixtures<\/li>\n<li>Characterization of oxidation and fragmentation products of peptides<\/li>\n<li>Study of ion-molecule reactions<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-123-3\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-123-3-0\"  class=\"panel-grid-cell\" ><div id=\"panel-123-3-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"6\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Sample Environment<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Electrospray and nanospray sources<\/li>\n<li>Solution concentration ~ 10\u207b\u2075 to 10\u207b\u2079 M, typically in a water: methanol mixture<\/li>\n<li>Ability to introduce solid, liquid, or gaseous neutral samples into the hexapod used as a collision cell.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-123-3-1\"  class=\"panel-grid-cell\" ><div id=\"panel-123-3-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"7\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Energy Range<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p><em>Infrared<\/em>\u00a0:<\/p>\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>5 to 20 \u00b5m (CLIO)<\/li>\n<li>2.5 to 5 \u00b5m (OPO\/OPA)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-123-4\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-123-4-0\"  class=\"panel-grid-cell\" ><div id=\"panel-123-4-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"8\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Detectors \/ Complementary Equipment<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Infrared-sensitive detectors<\/li>\n<li>OPO\/OPA tabletop laser<\/li>\n<li>CO\u2082 laser<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-123-4-1\"  class=\"panel-grid-cell\" ><div id=\"panel-123-4-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"9\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Beam Size<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<div class=\"flex max-w-full flex-col flex-grow\">\n<div class=\"min-h-8 text-message flex w-full flex-col items-end gap-2 whitespace-normal break-words [.text-message+&amp;]:mt-5\" dir=\"auto\" data-message-author-role=\"assistant\" data-message-id=\"d074e3f8-7e45-499f-8338-f19add58079f\" data-message-model-slug=\"gpt-4o-mini\">\n<div class=\"flex w-full flex-col gap-1 empty:hidden first:pt-[3px]\">\n<div class=\"markdown prose w-full break-words dark:prose-invert light\">\n<p>Adjustable.<\/p>\n<p>The infrared beam is focused within the ICR cell through a hole about 6 mm in diameter.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"mb-2 flex gap-3 empty:hidden -ml-2\">\n<div class=\"items-center justify-start rounded-xl p-1 flex\">\n<div class=\"flex items-center\"><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-123-5\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-123-5-0\"  class=\"panel-grid-cell\" ><div id=\"panel-123-5-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child\" data-index=\"10\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Technical Details<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>FT-ICR Mass Spectrometer: Equipped with electrospray and nanospray sources. The sample solution is introduced into the spectrometer using a syringe pump with a constant flow rate of about 120 \u00b5L\/h. Pressure is approximately 10\u207b\u00b9\u2070 Torr. Resolution is around 1,000,000 at m\/z 4000.<\/li>\n<li>OPO\/OPA Laser (Laser Vision): Includes a Nd pump laser, an OPO, and an OPA. KTP (KTiOPO\u2084) and KTA (KTiOAsO\u2084) crystals are used to sequentially change the wavelength to the desired value.<\/li>\n<li>Chemistry Laboratory: Used for sample preparation, equipped with a balance, ultrasonic bath, and Sorbonne.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><div id=\"panel-123-5-0-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"11\" ><div class=\"panel-widget-style panel-widget-style-for-123-5-0-1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Contact<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Head of Experiments : Debora Scuderi<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>","protected":false},"excerpt":{"rendered":"<p>Infrared Spectroscopy of Ions Integrated with Mass Spectrometry \/ 7T FT-ICR The room is equipped with a hybrid FT-ICR mass spectrometer featuring a 7T magnet (Bruker Apex Qe), coupled with the Free Electron Laser, an OPO\/OPA tabletop laser (2.5 -5 \u00b5m), and a CO2 laser (10.6 \u00b5m). This setup allows for deriving IR spectra of&hellip;&nbsp;<a href=\"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/en\/ft-icr-mass-spectrometer-at-very-high-resolution\/\" rel=\"bookmark\">Lire la suite &raquo;<span class=\"screen-reader-text\">FT-ICR Mass Spectrometer at Very High Resolution<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"off","neve_meta_content_width":100,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","footnotes":""},"class_list":["post-123","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages\/123","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/comments?post=123"}],"version-history":[{"count":2,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages\/123\/revisions"}],"predecessor-version":[{"id":125,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages\/123\/revisions\/125"}],"wp:attachment":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/media?parent=123"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}