{"id":132,"date":"2024-11-12T18:45:29","date_gmt":"2024-11-12T17:45:29","guid":{"rendered":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/?page_id=132"},"modified":"2024-11-12T18:45:29","modified_gmt":"2024-11-12T17:45:29","slug":"irmpd-in-3d-quadrupole-ion-trap","status":"publish","type":"page","link":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/en\/irmpd-in-3d-quadrupole-ion-trap\/","title":{"rendered":"IRMPD in 3D Quadrupole Ion Trap"},"content":{"rendered":"<div id=\"pl-132\"  class=\"panel-layout\" ><div id=\"pg-132-0\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-132-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-132-0-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"0\" ><div class=\"panel-widget-style panel-widget-style-for-132-0-0-0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">IRMPD in 3D Quadrupole Ion Trap  --  [E09]<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Infrared spectroscopy of ions integrated with mass spectrometry\/ESQUIRE 3000+<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><div id=\"pg-132-1\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-132-1-0\"  class=\"panel-grid-cell\" ><div id=\"panel-132-1-0-0\" class=\"so-panel widget widget_sow-image panel-first-child panel-last-child\" data-index=\"1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-132\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E9.png\" width=\"976\" height=\"655\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E9.png 976w, https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E9-300x201.png 300w, https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E9-768x515.png 768w, https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-content\/uploads\/sites\/6\/2024\/11\/E9-272x182.png 272w\" sizes=\"(max-width: 976px) 100vw, 976px\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><\/div><div id=\"pgc-132-1-1\"  class=\"panel-grid-cell\" ><div id=\"panel-132-1-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>The room is equipped with a Paul trap mass spectrometer (Esquire Bruker 3000+) that has been extensively modified to couple with the CLIO free electron laser, an OPO\/OPA tabletop laser, a CO2 laser, and an UV laser. An ion mobility device (DIMS) is also available on the ion trap. This setup allows for IR or UV spectra of ions to be derived, with isomeric forms separated by differential ion mobility beforehand. Ions are gas-phase ionized via an ESI source, and the ion trap is modified to introduce neutral molecules for ion-molecule reactions.<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-132-2\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-132-2-0\"  class=\"panel-grid-cell\" ><div id=\"panel-132-2-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child\" data-index=\"3\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Disciplines<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Molecular Physicochemistry<\/li>\n<li>Analytical Chemistry<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><div id=\"panel-132-2-0-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"4\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Complementary Techniques<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Tandem mass spectrometry (MS2 or MSn)<\/li>\n<li>UVPD spectroscopy (UV photodissociation)<\/li>\n<li>Ion mobility of the DIMS type<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-132-2-1\"  class=\"panel-grid-cell\" ><div id=\"panel-132-2-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"5\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Applications<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Characterization of reaction mechanisms via spectroscopy of reaction intermediates.<\/li>\n<li>Characterization of products in a complex mixture.<\/li>\n<li>Characterization of the nature of oxidation and fragmentation products of peptides.<\/li>\n<li>Characterization of chiral discrimination phenomena in complexes through UV-induced photofragmentation.<\/li>\n<li>Characterization of isomeric species within a mixture.<\/li>\n<li>Study of ion-molecule reactions of interstellar interest.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-132-3\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-132-3-0\"  class=\"panel-grid-cell\" ><div id=\"panel-132-3-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"6\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Sample Environment<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Electrospray source<\/li>\n<li>Solution concentration ~ 10<sup>-5<\/sup> to 10<sup>-6<\/sup> M, typically in a water:methanol mixture<\/li>\n<li>Possibility of introducing solid, liquid, or neutral gas samples into the ion trap.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-132-3-1\"  class=\"panel-grid-cell\" ><div id=\"panel-132-3-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"7\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Energy Range<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p><em>Infrared<\/em>\u00a0:<\/p>\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>5 to 20 \u00b5m (CLIO)<\/li>\n<li>2.5 to 5 \u00b5m (OPO\/OPA)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p><em>UV : <\/em>266 nm (soon to be 213 and 355 nm)<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-132-4\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-132-4-0\"  class=\"panel-grid-cell\" ><div id=\"panel-132-4-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"8\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Detectors \/ Complementary Equipment<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Infrared-sensitive detectors:<\/li>\n<li>OPO\/OPA tabletop laser (2.5-5 \u00b5m)<\/li>\n<li>UV laser (Litron) (@ 266 nm)<\/li>\n<li>CO2 laser (10.6 \u00b5m)<\/li>\n<li>Differential Ion Mobility Spectrometry (DIMS)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><\/div><div id=\"pgc-132-4-1\"  class=\"panel-grid-cell\" ><div id=\"panel-132-4-1-0\" class=\"so-panel widget widget_sow-editor panel-first-child panel-last-child\" data-index=\"9\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Beam Size<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<div class=\"flex max-w-full flex-col flex-grow\">\n<div class=\"min-h-8 text-message flex w-full flex-col items-end gap-2 whitespace-normal break-words [.text-message+&amp;]:mt-5\" dir=\"auto\" data-message-author-role=\"assistant\" data-message-id=\"d074e3f8-7e45-499f-8338-f19add58079f\" data-message-model-slug=\"gpt-4o-mini\">\n<div class=\"flex w-full flex-col gap-1 empty:hidden first:pt-[3px]\">\n<div class=\"markdown prose w-full break-words dark:prose-invert light\">\n<p>Adjustable.<\/p>\n<p>The infrared beam is focused within the annular electrode, which has been pierced with a hole approximately 2 mm in diameter.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"mb-2 flex gap-3 empty:hidden -ml-2\">\n<div class=\"items-center justify-start rounded-xl p-1 flex\">\n<div class=\"flex items-center\"><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div><\/div><\/div><\/div><div id=\"pg-132-5\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-132-5-0\"  class=\"panel-grid-cell\" ><div id=\"panel-132-5-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child\" data-index=\"10\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Technical Details<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>The mass spectrometer is of the Paul trap type (Bruker Esquire 3000+) equipped with an electrospray source. It is a quadrupole trap (Paul trap) coupled with an atmospheric pressure ESI source. Resolution is approximately 5000 at m\/z 3000. Pressure is around 10^-5 Torr.<\/li>\n<li>OPO\/OPA laser (Laser Vision). The system consists of a Nd pump laser, followed by an OPO and an OPA. KTP (KTiOPO4) and KTA (KTioAsO4) crystals are used to successively change the starting wavelength until the desired one is achieved.<\/li>\n<li>UV Laser TRLi 850 (Litron). The laser, with an output energy at 1064 nm (approximately 130 mJ\/pulse), can be coupled with second, third, fourth, and fifth harmonic modules.<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><div id=\"panel-132-5-0-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"11\" ><div class=\"panel-widget-style panel-widget-style-for-132-5-0-1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Contact<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Head of Experiments : Debora Scuderi<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>","protected":false},"excerpt":{"rendered":"<p>Infrared spectroscopy of ions integrated with mass spectrometry\/ESQUIRE 3000+ The room is equipped with a Paul trap mass spectrometer (Esquire Bruker 3000+) that has been extensively modified to couple with the CLIO free electron laser, an OPO\/OPA tabletop laser, a CO2 laser, and an UV laser. An ion mobility device (DIMS) is also available on&hellip;&nbsp;<a href=\"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/en\/irmpd-in-3d-quadrupole-ion-trap\/\" rel=\"bookmark\">Lire la suite &raquo;<span class=\"screen-reader-text\">IRMPD in 3D Quadrupole Ion Trap<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"off","neve_meta_content_width":100,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","footnotes":""},"class_list":["post-132","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages\/132","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/comments?post=132"}],"version-history":[{"count":2,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages\/132\/revisions"}],"predecessor-version":[{"id":134,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/pages\/132\/revisions\/134"}],"wp:attachment":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/clio\/wp-json\/wp\/v2\/media?parent=132"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}