{"id":296,"date":"2024-10-29T18:00:57","date_gmt":"2024-10-29T17:00:57","guid":{"rendered":"http:\/\/wwww.icp.universite-paris-saclay.fr\/temic\/?page_id=296"},"modified":"2024-11-19T16:59:42","modified_gmt":"2024-11-19T15:59:42","slug":"absorption-transitoire","status":"publish","type":"page","link":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/instruments-remarquables\/absorption-transitoire\/","title":{"rendered":"Absorption transitoire"},"content":{"rendered":"<div id=\"pl-296\"  class=\"panel-layout\" ><div id=\"pg-296-0\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-296-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-296-0-0-0\" class=\"so-panel widget widget_sow-editor panel-first-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Absorption transitoire \u00e0 l\u2019\u00e9chelle femtoseconde<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>L\u2019exp\u00e9rience d\u2019absorption transitoire permet de mesurer sur une \u00e9chelle de temps allant d\u2019une centaine de femtosecondes \u00e0 quelques centaines de picosecondes les changements du spectre d\u2019absorption visible d\u2019un \u00e9chantillon, liquide ou solide, induits par une impulsion laser femtoseconde.<\/p>\n<\/div>\n<\/div><\/div><div id=\"panel-296-0-0-1\" class=\"so-panel widget widget_sow-editor\" data-index=\"1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Principe de l\u2019exp\u00e9rience<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Il s\u2019agit d\u2019une exp\u00e9rience de type \u00ab\u00a0pompe -sonde\u00a0\u00bb. Une impulsion laser \u00ab\u00a0pompe\u00a0\u00bb g\u00e9n\u00e8re des excitations et\/ou des ionisations dans l\u2019\u00e9chantillon et une impulsion \u00ab\u00a0blanche\u00a0\u00bb, la \u00ab\u00a0sonde\u00a0\u00bb, permet de mesurer le spectre d\u2019absorption de l\u2019\u00e9chantillon \u00e0 un temps donn\u00e9 par rapport \u00e0 l\u2019impulsion \u00ab\u00a0pompe\u00a0\u00bb. En comparant l\u2019absorption de l\u2019\u00e9chantillon apr\u00e8s et avant l\u2019impulsion laser \u00ab\u00a0pompe\u00a0\u00bb, le spectre d\u2019absorption transitoire pour un d\u00e9lai \u00ab\u00a0pompe-sonde\u00a0\u00bb donne\u0301 est obtenu. Le d\u00e9lai \u00ab\u00a0pompe-sonde\u00a0\u00bb Dt est contr\u00f4le\u0301 par une ligne a\u0300 retard qui modifie la longueur du parcours optique de la \u00ab\u00a0sonde\u00a0\u00bb par rapport a\u0300 la \u00ab\u00a0pompe\u00a0\u00bb\u00a0; en faisant varier ce d\u00e9lai, il est possible d\u2019\u00e9tudier les dynamiques et cin\u00e9tiques d\u2019\u00e9volution ultra-rapide du syst\u00e8me.<\/p>\n<\/div>\n<\/div><\/div><div id=\"panel-296-0-0-2\" class=\"so-panel widget widget_sow-image\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-296\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans.png\" width=\"945\" height=\"308\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans.png 945w, https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans-300x98.png 300w, https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans-768x250.png 768w\" sizes=\"(max-width: 945px) 100vw, 945px\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><div id=\"panel-296-0-0-3\" class=\"so-panel widget widget_sow-editor\" data-index=\"3\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: center;\"><em>Principe de l\u2019exp\u00e9rience \u00ab pompe-sonde \u00bb d\u2019absorption transitoire femtoseconde\u00a0(GSH\/GTH\u00a0: g\u00e9n\u00e9ration de la seconde \/ troisi\u00e8me harmonique, CLB\u00a0: continuum de lumi\u00e8re blanche)<\/em><\/p>\n<\/div>\n<\/div><\/div><div id=\"panel-296-0-0-4\" class=\"so-panel widget widget_sow-editor\" data-index=\"4\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Caract\u00e9ristiques<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li><strong>Source laser<\/strong>\u00a0: le laser utilis\u00e9 est un laser Titane:Saphir amplifi\u00e9 commercial (<em>Amplitude<\/em>) produisant des impulsions centr\u00e9e \u00e0 780 nm ayant une \u00e9nergie de ~2mJ, une dur\u00e9e de ~130 fs, \u00e0 un taux de r\u00e9p\u00e9tition de 1 kHz, mais seulement 640 \u00b5J de l\u2019\u00e9nergie est utilis\u00e9e pour le montage d\u2019absorption transitoire.<\/li>\n<li><strong>G\u00e9n\u00e9rateur d\u2019harmoniques<\/strong>\u00a0: 90% de l\u2019\u00e9nergie du faisceau laser sont utilis\u00e9e pour le faisceau \u00ab\u00a0pompe\u00a0\u00bb et envoy\u00e9e vers un g\u00e9n\u00e9rateur d\u2019harmoniques (<em>Spectra Physics<\/em>) pour produire soit la deuxi\u00e8me harmonique (GSH) \u00e0 390 nm soit la troisi\u00e8me harmonique (GTH) \u00e0 260 nm.<\/li>\n<li><strong>Continuum de lumi\u00e8re blanche<\/strong>\u00a0: 10% de l\u2019\u00e9nergie du faisceau laser sert \u00e0 produire un continuum de lumi\u00e8re blanche (CLB) par focalisation dans une lame de silice fondue ou de saphir qui va fournir l\u2019impulsion \u00ab\u00a0sonde\u00a0\u00bb, mais aussi une impulsion de r\u00e9f\u00e9rence permettant de prendre en compte les fluctuations du laser.<\/li>\n<li><strong>Ligne \u00e0 retard<\/strong>\u00a0: une platine de translation (<em>Micro-Contr\u00f4le<\/em>) de longueur 20 cm avec des pas de 1 \u00b5m permet des \u00e9tudes jusqu\u2019\u00e0 la nanoseconde.<\/li>\n<li><strong>D\u00e9tection<\/strong>\u00a0: un spectrographe muni d\u2019une tourelle 3 r\u00e9seaux (<em>ACTON<\/em>) coupl\u00e9 \u00e0 une cam\u00e9ra CCD 1300 x 400 pixels (<em>Princeton Instruments<\/em>) permet l\u2019enregistrement simultan\u00e9 des faisceaux sonde et r\u00e9f\u00e9rence sur une gamme spectrale entre 300 nm et 850 nm.<\/li>\n<li><strong>Echantillons<\/strong>\u00a0: il y a possibilit\u00e9 de travailler avec des \u00e9chantillons liquides (en cellules en quartz de parcours optique 1 mm, \u00e0 circulation ou non, ou sous forme de jet laminaire de 300 \u00b5m), ou avec des \u00e9chantillons solides (lames minces ou films support\u00e9s ou non).<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><div id=\"panel-296-0-0-5\" class=\"so-panel widget widget_sow-editor\" data-index=\"5\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Exemples de syst\u00e8mes \u00e9tudi\u00e9s <\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li style=\"list-style-type: none;\">\n<ul>\n<li>Solvatation de l\u2019\u00e9lectron produit par photo-ionisation du solvant<\/li>\n<li>Dynamique des \u00e9tats excit\u00e9s de compos\u00e9s mol\u00e9culaires<\/li>\n<li>Transfert de proton \u00e0 l\u2019\u00e9tat excit\u00e9 entre la pyranine et l\u2019eau (TP de M2)<\/li>\n<li>Transfert d\u2019\u00e9lectron au sein de complexes porphyrines-polyoxom\u00e9tallates<\/li>\n<li>Dynamique des porteurs de charge photog\u00e9n\u00e9r\u00e9s dans des semi-conducteurs<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/div>\n<\/div><\/div><div id=\"panel-296-0-0-6\" class=\"so-panel widget widget_sow-image\" data-index=\"6\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-296\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans2.png\" width=\"916\" height=\"279\" srcset=\"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans2.png 916w, https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans2-300x91.png 300w, https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-content\/uploads\/sites\/5\/2024\/10\/AbsTrans2-768x234.png 768w\" sizes=\"(max-width: 916px) 100vw, 916px\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><div id=\"panel-296-0-0-7\" class=\"so-panel widget widget_sow-editor\" data-index=\"7\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: center;\"><em>Exemples de signaux (A spectres et B cin\u00e9tiques) obtenus lors de l\u2019\u00e9tude du transfert de proton \u00e0 l\u2019\u00e9tat excit\u00e9 entre la pyranine et l\u2019eau [<a href=\"https:\/\/universite-paris-saclay.hal.science\/ICPO\/hal-02991490v1\">Changenet2020<\/a>]<\/em><\/p>\n<\/div>\n<\/div><\/div><div id=\"panel-296-0-0-8\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"8\" ><div class=\"panel-widget-style panel-widget-style-for-296-0-0-8\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Responsable scientifique <\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p><a href=\"https:\/\/www.icp.universite-paris-saclay.fr\/contact-il\/\" target=\"_blank\" rel=\"noopener\">Isabelle Lampre<\/a> (PR)<\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>","protected":false},"excerpt":{"rendered":"<p>L\u2019exp\u00e9rience d\u2019absorption transitoire permet de mesurer sur une \u00e9chelle de temps allant d\u2019une centaine de femtosecondes \u00e0 quelques centaines de picosecondes les changements du spectre d\u2019absorption visible d\u2019un \u00e9chantillon, liquide ou solide, induits par une impulsion laser femtoseconde. Il s\u2019agit d\u2019une exp\u00e9rience de type \u00ab\u00a0pompe -sonde\u00a0\u00bb. Une impulsion laser \u00ab\u00a0pompe\u00a0\u00bb g\u00e9n\u00e8re des excitations et\/ou des&hellip;&nbsp;<a href=\"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/instruments-remarquables\/absorption-transitoire\/\" rel=\"bookmark\">Lire la suite &raquo;<span class=\"screen-reader-text\">Absorption transitoire<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":253,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"off","neve_meta_content_width":100,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","footnotes":""},"class_list":["post-296","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/pages\/296","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/comments?post=296"}],"version-history":[{"count":8,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/pages\/296\/revisions"}],"predecessor-version":[{"id":404,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/pages\/296\/revisions\/404"}],"up":[{"embeddable":true,"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/pages\/253"}],"wp:attachment":[{"href":"https:\/\/www.icp.universite-paris-saclay.fr\/temic\/wp-json\/wp\/v2\/media?parent=296"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}